I am curious about those Thunderbolts figures. They've been rumored for a while, but we haven't heard even a peep from Hasbro. I'd still love to see them, as well as Bucky/Ghost. If only because, out of all the characters, the Thunderbolts/New Avengers seem to be the most likely candidates for Doom fodder in Doomsday.
As for BND- I'm sure I'll pick up Spidey, even if I wait a bit. Hulk is gonna depend. The only Hulk I have is the AoU 2 pack version, which I like well enough, but wouldn't mind an upgrade with the new joints and such. But it would probably depend on color, since I'm sure one (green) is more likely to make future appearances and not just be a one-off. That basic Scorpion is interesting; wonder if the helmet is accurate or was an old design choice that was nixed in the final product. Didn't see a helmet in the trailer, but we know they don't always reflect the finished CGI.
For Punisher- I haven't really kept up on the costume differences, if any, between BND and OLK. Are they close enough that, theoretically, Hasbro could just include a swappable head to make both versions in one?